Xenon tetrafluoride XeF4 is a planar molecule beonging to the D4h Point group. Xe + 2 F 2 → XeF 4. The geometry of XeF 4 is square planar with symmetric electron region distribution. Back to Molecular Geometries & Polarity Tutorial: Molecular Geometry & Polarity Tutorial. The geometry of Xeof₄ is square pyramidal. Xenon tetrafluoride is a chemical compound with chemical formula XeF 4.It was the first discovered binary compound of a noble gas. VSEPR theory predicts that XeF4 is square planar. The central Xe atom has 4 bond pairs of electrons and two lone pairs of electrons. With this, they will acquire a stable state. The molecular geometry of XeF4 is square planar. The molecular polarity is determined by the vector sum (magnitude and … What's the electron pair geometry & molecular geometry of XeF4? Xenon Tetrafluoride on Wikipedia. Therefore the shape of XeF4 is square planar. Therefore this molecule is nonpolar. It is produced by the chemical reaction of xenon with fluorine, F 2, according to the chemical equation:. The symmetry operations are shown interactively in 3D XeF 4 consists of two lone pair electrons. As we have learned before the s-orbital will be used by the central atom, the hybrid orbitals will be mixed via its p-orbitals … Author has 3.2K answers and 1.4M answer views. With the two lone pairs placed axially opposite to each other, the overall structure of the concerned molecule is symmetric. XeF 4 Molecular Geometry And Bond Angles. Thus, we have octahedral electron pair geometry, and square planar molecular geometry. There are six electron pairs around the central atom (Xe), four of which are bonding, and two are lone pairs. Now if we follow the VSEPR theory, the net electronic repulsions has to be minimum. It undergoes sp3d2 hybridization which results in octahedral electron geometry and square planar molecular geometry. This reaction is exothermic, releasing an energy of 251 kJ/mol.. Xenon tetrafluoride is a colorless crystalline substance. Xenon Tetrafluoride Class: AX(sub)4E2 # of atoms and lone pairs on central atom: 6 # of atoms bonded to central atom: 4